It was originally performed by the Clovers, who took it to number 23 on the US as well as R&B charts that year. Love Potion No. Their version reached number three on the U.S. Billboard Hot 100 and number two on Cash Box during the winter of 1965. The film takes its name from the 1959 hit song, " Love Potion No. The story is about a love potion, that enables a person to make people of the opposite sex … Herb Alpert and The Tijuana Brass did an … "Love Potion No. 9 ". 9 is a 1992 American romantic comedy film starring Tate Donovan and Sandra Bullock. The song was recorded by the Searchers in 1964. 9" is a song written in 1959 by Jerry Leiber and Mike Stoller.